Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2023 Nov 21;52(45):16680-16687.
doi: 10.1039/d3dt02765a.

Bicyclic (alkyl)(amino)carbene (BICAAC)-supported phosphinidenes

Ritu Yadav  1 , Bindusagar Das  1 , Ashi Singh  1 , Anmol  1 , Ankita Sharma  1 , Chinmoy Majumder  1 , Subrata Kundu  1
Affiliations

Bicyclic (alkyl)(amino)carbene (BICAAC)-supported phosphinidenes

Ritu Yadav et al. Dalton Trans. .

Abstract

Herein, the synthesis and characterization of bicyclic (alkyl)(amino)carbene (BICAAC)-stabilized phosphinidenes (1-4) are reported. Compounds 1-3 were obtained by reacting trihalophosphine [PX3, X = Cl (1), Br (2), I (3)] with BICAAC in THF. A BICAAC-stabilized bis-phosphinidene (4) was obtained from the reduction of compound 2. All four compounds were characterized by X-ray crystallography and heteronuclear NMR spectroscopy. Theoretical calculations indicated the predominant C(carbene)P double bond characteristic in compounds 1-4.

PubMed Disclaimer

LinkOut - more resources