Ultrasound for the degradation of endocrine disrupting compounds in aqueous solution: A review on mechanisms, influence of operating parameters and cost estimation

Abstract

Availability of drinking water is one of the basic humanitarian goals but remains as a grand challenge that the world is facing today. Currently, water bodies are contaminated not only with conventional pollutants but also with numerous recalcitrant pollutants, such as PPCPs, endocrine disrupting compounds, etc. These emerging pollutants require special attention because of their toxicity to living organisms, bio-resistant and can sustain even after primary and secondary treatments of wastewater. Among different treatment technologies, sonolysis is found to be an innovative and promising technique for the treatment of emerging pollutants present in aqueous solution. Sonolysis is the use of ultrasound to enhance or alter chemical reactions by the formation of free radicals and shock waves which ultimately helps in degradation of pollutants. This review summarizes several studies in the sonochemical literature, including mechanisms of sonochemical process, physical and chemical effects of ultrasound, and the influence of several process variables such as ultrasound frequency, power density, temperature and pH of the medium on degradation performance for endocrine disrupting compounds. In addition, this review highlighted techno-economic perspectives focusing on the total cost required for translating the ultrasound-based processes on a large scale. Overall, the objective of this study is to exhibit a critical review of information available in the literature to encourage and promote future research on sonolysis for the degradation of Endocrine Disrupting Compounds (EDCs).

Keywords: Acoustic cavitation; Advanced oxidation processes (AOPs); Bubble dynamics; Cost estimation; Sonolysis.