Smart colorimetric sensing films based on carboxymethyl cellulose incorporated with a natural pH indicator

Abstract

This study aimed to combine various natural pH indicators of anthocyanin from Karanda (CA) with anthocyanin from butterfly pea flower (BA) or curcumin (CC) to improve the sensitivity of CA. CA75/BA25 and CA25/CC75 enhanced the sensitivity of the endpoint colour change of CA. A smart colorimetric sensing film was also developed and characterised by loading different natural pH indicators on carboxymethyl cellulose (CMC) films. The addition of different natural pH indicators increased the thickness, elongation, colour (a* and b* values), and contact angle of CMC films (p < 0.05). However, the tensile strength, water vapour permeability, film solubility, light transmission, and L* value decreased when different natural pH indicators were added (p < 0.05). The indicator films demonstrated enhanced antioxidant capacity and thermal stability. The FTIR spectra showed that natural pH indicators were successfully immobilised into the CMC films. Notably, the CMC/CA75/BA25 film was the most sensitive film to changes in volatile ammonia and different pH buffer solutions. The CMC/CA75/BA25 film changed from purple to green with exposure to ammonia solution and from pink to purple to blue to green with increasing pH. Therefore, the CMC/CA75/BA25 film has potential as a colorimetric sensing film, providing a more accurate assessment result.

Keywords: Agricultural wastes; Anthocyanin; Carissa carandas L.; Curcumin; Smart colorimetric sensing films.