Facile synthesis of lignin-based Fe-MOF for fast adsorption of methyl orange

Abstract

To rapidly remove dyes from wastewater, iron-based metal-organic frameworks modified with phenolated lignin (NH₂-MIL@L) were prepared by a one-step hydrothermal method. Analyses of the chemical structure and adsorption mechanism of the NH₂-MIL@L proved the successful introduction of lignin and the enhancement of its adsorption sites. Compared with NH₂-MIL-101-Fe without phenolated lignin, the modification with lignin increased the methyl orange (MO) adsorption rate of NH₂-MIL@L. For the best adsorbent, NH₂-MIL@L₄, the MO adsorption efficiency in MO solution reached 95.09% within 5 min. NH₂-MIL@L₄ reached adsorption equilibrium within 90 min, exhibiting an MO adsorption capacity of 195.31 mg/g. The process followed pseudo-second-order kinetics and the Dubinin-Radushkevich model. MO adsorption efficiency of NH₂-MIL@L₄ was maintained at 89.87% after six adsorption-desorption cycles. In mixed solutions of MO and methylene blue (MB), NH₂-MIL@L₄ achieved an MO adsorption of 94.02% at 5 min and reached MO adsorption equilibrium within 15 min with an MO adsorption capacity of 438.6 mg/g, while the MB adsorption equilibrium was established at 90 min with an MB adsorption rate and capacity of 95.60% and 481.34 mg/g, respectively. NH₂-MIL@L₄ sustained its excellent adsorption efficiency after six adsorption-desorption cycles (91.2% for MO and 93.4% for MB). The process of MO adsorption by NH₂-MIL@L₄ followed the Temkin model and pseudo-second-order kinetics, while MB adsorption followed the Dubinin-Radushkevich model and pseudo-second-order kinetics. Electrostatic interactions, π-π interactions, hydrogen bonding, and synergistic interactions affected the MO adsorption process of NH₂-MIL@L₄.

Keywords: Dye wastewater treatment; Lignin-based metal-organic frameworks; Rapid adsorption; Renewable.