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. 2024 Mar 6;9(Pt 3):x240186.
doi: 10.1107/S241431462400186X. eCollection 2024 Mar.

Bis[ S-octyl 3-(2-methyl-propyl-idene)di-thio-carb-az-ato-κ2N3, S]nickel(II)

Sultana Shakila Khan  1 , Md Belayet Hossain Howlader  1 , Md Chanmiya Sheikh  2 , Ryuta Miyatake  3 , Ennio Zangrando  4
Affiliations

Bis[ S-octyl 3-(2-methyl-propyl-idene)di-thio-carb-az-ato-κ2N3, S]nickel(II)

Sultana Shakila Khan et al. IUCrdata. .

Abstract

The central NiII atom in the title complex, [Ni(C13H25N2S2)2], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni-N and Ni-S bond lenghts are 1.9193 (14) and 2.1788 (5) Å, respectively, with a chelating N-Ni-S bond angle of 86.05 (4)°. These data are compared with those measured for similar di-thio-carbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenyl-ethyl-idene derivative where the ligands are bound cis relative to one another.

Keywords: NiII complex; crystal structure; di­thio­carbazato ligand; octyl alkyl chain; trans configuration complex.

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Figures

Figure 1
Figure 1
Mol­ecular structure of the title complex [Ni(C13H25N2S2)2] with displace­ment ellipsoids drawn at the 50% probability level.
Figure 2
Figure 2
View of the crystal packing of the title complex [Ni(C13H25N2S2)2] in a view along [102]; H atoms are not shown for clarity.
See this image and copyright information in PMC

References

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    1. Begum, K., Zangrando, E., Begum, M. S., Sheikh, C. & Miyatake, R. (2018). IUCrData, 3, x181684.
    1. Begum, M. S., Zangrando, E., Howlader, M. B. H., Sheikh, M. C., Miyatake, R., Hossain, M. M., Alam, M. M. & Hasnat, M. A. (2016). Polyhedron, 105, 56–61.
    1. Begum, M. S., Zangrando, E., Sheikh, M. C., Miyatake, R., Howlader, M. B. H., Rahman, M. N. & Ghosh, A. (2017). Transit. Met. Chem. 42, 553–563.
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