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. 2024 May 21;60(42):5522-5525.
doi: 10.1039/d4cc00812j.

Triptycene-based diiron(II) mesocates: spin-crossover in solution

Riccardo Mobili  1   2 , Giovanni Preda  1 , Daniele Dondi  1 , Enrico Monzani  1 , Dhanalakshmi Vadivel  1 , Chiara Massera  3 , Dario Pasini  1 , Valeria Amendola  1
Affiliations

Triptycene-based diiron(II) mesocates: spin-crossover in solution

Riccardo Mobili et al. Chem Commun (Camb). .

Abstract

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).

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