Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2024 May 3;29(9):2125.
doi: 10.3390/molecules29092125.

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

Vladimir A Bushuev  1   2 , Natalia V Gogoleva  1 , Stanislav A Nikolaevskii  1 , Sergey V Novichihin  3 , Dmitriy S Yambulatov  1 , Mikhail A Kiskin  1 , Igor L Eremenko  1
Affiliations

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

Vladimir A Bushuev et al. Molecules. .

Abstract

Interaction of the pre-organized complex of iron(II) trimethylacetate and 1,10-phenanthroline (phen) [Fe2(piv)4(phen)2] (1) (piv = (Me)3CCO2-)) with 1,6-diaminohexane (dahx) in anhydrous acetonitrile yielded a 1D coordination polymer [Fe3O(piv)6(dahx)1.5]n (2) and an organic salt of pivalic acid (H2dahx)(piv)2 (3). The structure of the obtained compounds was determined by single-crystal X-ray diffraction analysis. The phase purity of the complexes was determined by powder X-ray diffraction analysis. According to the single-crystal X-ray analysis, coordination polymer 2 is formed due to the binding of a triangular carboxylate core {Fe3(μ3-O)(μ-piv)6} with an aliphatic diamine ligand. Thermal behavior was investigated for compounds 1 and 2 in an argon atmosphere.

Keywords: aliphatic diamines; carboxylate complexes; coordination polymers; iron complexes; molecular structure.

PubMed Disclaimer

Conflict of interest statement

The authors declare no conflicts of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results.

Figures

Scheme 1
Scheme 1
The formation of complexes 1, 2 and an organic salt 3.
Figure 1
Figure 1
Molecular structure (a) and crystal packing (b) of 1 ((a)—thermal ellipsoids with a probability of 30%; (a,b)—hydrogen atoms are not shown, π–π contacts are indicated by dotted lines between the centroids of the aromatic rings N2C26–C30 and N3C33–C37).
Figure 1
Figure 1
Molecular structure (a) and crystal packing (b) of 1 ((a)—thermal ellipsoids with a probability of 30%; (a,b)—hydrogen atoms are not shown, π–π contacts are indicated by dotted lines between the centroids of the aromatic rings N2C26–C30 and N3C33–C37).
Figure 2
Figure 2
Fragments of 1D polymer structure 2: (a)—binding of triangular fragments {Fe3O(piv)6} by μ-bridging molecules of 1,6-diaminohexane, (b)—fragment of a chain formed by binding {Fe3O(piv)6} through Fe1 and Fe2 atoms along axes 0c, (c)—fragment of corrugated tape, (d)—projection of the tape packing on the 0ab plane (hydrogen atoms and CH3 groups are not shown).
Figure 3
Figure 3
Fragment of the crystal packing of compound 3 (thermal ellipsoids with a probability of 30%, hydrogen atoms at CH3 groups are not shown, N–H…O and C–H…O interactions are indicated by the dotted line).
Figure 4
Figure 4
Comparison of experimental (A, blue line) and theoretical (B, red line) diffraction patterns for sample 1.
Figure 5
Figure 5
Comparison of experimental (A, blue line) and theoretical (B, red line) diffraction patterns for sample 2.
Figure 6
Figure 6
TGA (blue) and DTA (red) curves for complex 1.
Figure 7
Figure 7
TGA (blue) and DTA (red) curves for complex 2.
See this image and copyright information in PMC

Similar articles

See all similar articles

References

    1. Agafonov M.A., Alexandrov E.V., Artyukhova N.A., Bekmukhamedov G.E., Blatov V.A., Butova V.V., Gayfulin Y.M., Garibyan A.A., Gafurov Z.N., Gorbunova Y.G., et al. Metal-Organic Frameworks in Russia: From the Synthesis and Structure to Functional Properties and Materials. J. Struct. Chem. 2022;63:671–843. doi: 10.1134/S0022476622050018. - DOI
    1. Dulcevscaia G.M., Filippova I.G., Speldrich M., van Leusen J., Kravtsov V.C., Baca S.G., Kögerler P., Liu S.-X., Decurtins S. Cluster-Based Networks: 1D and 2D Coordination Polymers Based on {MnFe2(Μ3-O)}-Type Clusters. Inorg. Chem. 2012;51:5110–5117. doi: 10.1021/ic202644t. - DOI - PubMed
    1. Lytvynenko A.S., Kolotilov S.V., Kiskin M.A., Cador O., Golhen S., Aleksandrov G.G., Mishura A.M., Titov V.E., Ouahab L., Eremenko I.L., et al. Redox-Active Porous Coordination Polymers Prepared by Trinuclear Heterometallic Pivalate Linking with the Redox-Active Nickel(II) Complex: Synthesis, Structure, Magnetic and Redox Properties, and Electrocatalytic Activity in Organic Compound Dehalogenatio. Inorg. Chem. 2014;53:4970–4979. doi: 10.1021/ic403167m. - DOI - PubMed
    1. Polunin R.A., Kolotilov S.V., Kiskin M.A., Cador O., Golhen S., Shvets O.V., Ouahab L., Dobrokhotova Z.V., Ovcharenko V.I., Eremenko I.L., et al. V Structural Flexibility and Sorption Properties of 2D Porous Coordination Polymers Constructed from Trinuclear Heterometallic Pivalates and 4,4′-Bipyridine. Eur. J. Inorg. Chem. 2011;2011:4985–4992. doi: 10.1002/ejic.201100791. - DOI
    1. Petrov P.A., Nikolaevskii S.A., Yambulatov D.S., Starikova A.A., Sukhikh T.S., Kiskin M.A., Sokolov M.N., Eremenko I.L. Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism. Russ. J. Inorg. Chem. 2023;68:1255–1264. doi: 10.1134/S0036023623601460. - DOI