Chitosan as Support Material for Metal-Organic Framework based Catalysts

Abstract

Turning waste into valuable products is one of the main challenges of the chemical industry. In this work, chitosan (CS), an abundant, low-cost, and non-toxic biopolymer derived from chitin, was reshaped into beads of ~3 mm. Their suitability as a support material for active phase catalyst materials was tested for a zirconium-based Metal-Organic Framework (MOF) with incorporated Pt, namely UiO-67-Pt. Its incorporation was investigated via two procedures: a one-pot synthesis (OPS) and a post-synthetic functionalization (PSF) synthesis method. Scanning electron microscopy (SEM) images show good UiO-67-Pt dispersion throughout the CS beads for the one-pot synthesized material (UiO-67-Pt-OPS@CS). However, this uniform dispersion was not observed for the post-synthetically functionalized material (UiO-67-Pt-PSF@CS). The success of the implementation of UiO-67-Pt was evaluated with ultraviolet-visible and infrared spectroscopy for both composite materials. Thermogravimetric analysis (TGA) reveals higher thermal stabilities for UiO-67-Pt-OPS@CS composite beads in comparison to pure CS beads, but not for UiO-67-Pt-PSF@CS. The study provides valuable insights into the potential of chitosan as a green, bead-shaped support material for MOFs, offering flexibility in their incorporation through different synthesis routes. It further contributes to the broader goal of the sustainable and eco-friendly design of a new generation of catalysts made from waste materials, which will be the topic of future studies.

Keywords: chitosan; composite material; metal-organic framework; synthesis.