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. 2024 Jul 22;63(29):13186-13190.
doi: 10.1021/acs.inorgchem.4c01884. Epub 2024 Jul 8.

Trigonal-Bipyramidal Pt(0) and Pd(0) Anions

Hajime Kameo  1 , Tokoro Miyazaki  1 , Yoshihiro Shimoyama  2 , Ayaka Asada  1 , Daisuke Izumi  1 , Hiroyuki Matsuzaka  1 , Didier Bourissou  3
Affiliations

Trigonal-Bipyramidal Pt(0) and Pd(0) Anions

Hajime Kameo et al. Inorg Chem. .

Abstract

Anionic Pt(0) and Pd(0) complexes with unprecedented trigonal-bipyramidal geometry have been prepared and thoroughly characterized by experimental and computational means. Coordination of a σ-acceptor borane moiety supported by three phosphine buttresses enhances the electrophilicity of M(0) and triggers the binding of soft anions (X = Br, I, CN).

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