Tunable Exciton Polaritons in Band-Gap Engineered Hexagonal Boron Nitride

Abstract

We show that hexagonal boron nitride (hBN), a two-dimensional insulator, when subjected to an external superlattice potential forms a paradigm for electrostatically tunable excitons in the near- and mid-ultraviolet (UV). With a combination of analytical and numerical methods, we see that the imposed potential has three consequences: (i) It renormalizes the effective mass tensor, leading to anisotropic effective masses. (ii) It renormalizes the band gap, eventually reducing it. (iii) It reduces the exciton binding energies. All these consequences depend on a single dimensionless parameter, which includes the product of strength of the external potential with its period. In addition to the excitonic energy levels, we compute the optical conductivity along two orthogonal directions and from it the absorption spectrum. The results for the latter show that our system is able to mimic a grid polarizer. These characteristics make one-dimensional hBN superlattices a viable and meaningful platform for fine-tuned polaritonics in the UV to visible spectral range.

Keywords: exciton polaritons; hexagonal boron nitride; photonics; subgap optical response; super lattice.