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. 2024 Sep 5;60(72):9793-9796.
doi: 10.1039/d4cc03275f.

(Phosphino)(stannyl)carbene

Rui Wei  1 , Xin-Feng Wang  1 , Chaopeng Hu  1 , Liu Leo Liu  1
Affiliations

(Phosphino)(stannyl)carbene

Rui Wei et al. Chem Commun (Camb). .

Abstract

The synthesis of a (phosphino)(stannyl)carbene is documented. The combination of phosphino and stannyl substituents imparts a highly ambiphilic nature to this carbene, enabling reactions with cyanide, isocyanide, and carbon monoxide. This leads to rare stannylketenimines and a stannylketene.

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