Mini-review on lignin-based self-healing polymer

Abstract

Lignin, a biopolymer derived from plant biomass, is recognized as a highly promising substance for developing self-healing polymers owing to its dynamic linkages and functional groups. This paper provides a thorough review of lignin-based self-healing polymer, from the process of extracting lignin, chemical modification, synthesis techniques such as via reversible addition-fragmentation chain transfer (RAFT) polymerization, crosslinking with polymers like polyvinyl alcohol (PVA) and chitosan, and reactions with isocyanates to create lignin-based networks with reversible interactions. This work also summarizes the optimization of self-healing ability, such as including dynamic copolymers, encapsulating healing agents like dicyclopentadiene and polycaprolactone (PCL), and chain extenders with disulfide or Diels-Alder (DA) moieties. The material's characterization focuses on its capacity to recover via hydrogen bonding and dynamic re-associations, improved mechanical properties from lignin's rigid structure, and enhanced temperature resistance. Primary obstacles involve the optimization of lignin extraction, enhancement of polymer compatibility, and the establishment of efficient procedures for synthesis and characterization. Overall, lignin shows great potential as a renewable component of self-healing polymers, with plenty of opportunities for further development.

Keywords: Hydrogen bond; Lignin; Self-healing polymers.