A review of advancements in humic acid removal: Insights into adsorption techniques and hybrid solutions

Abstract

Humic acid (HA) is a prominent contaminant in wastewater, and its elimination is crucial to ensure purified drinking water. A variety of sources of HA in wastewater exist, ranging from agricultural runoff, industrial discharges, and natural decomposition. Adsorption is a technique that has been heavily investigated in this direction. The process complexities, technological advancements, and sustainable approaches are discussed in this review. A range of adsorbents can be employed for HA removal, including modified membranes, carbon nanotubes (CNTs), clay nanoparticles, and acid-modified natural materials. This work compares the effectiveness of the preceding adsorbents along with their advantages and limitations. This review also discusses the optimization of various process parameters, such as pH, ionic strength, and temperature, with an emphasis on response surface methodology for process optimization. Furthermore, the challenges and limitations associated with each removal technique are discussed, along with the potential areas for improvement and future directions in the field of wastewater treatment.

Keywords: Humic acid; Optimization models; Remediation; Removal techniques; Wastewater treatment.