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. 2024 Sep 6;9(Pt 9):x240849.
doi: 10.1107/S2414314624008496. eCollection 2024 Sep.

catena-Poly[[(8-amino-quinoline)-cobalt(II)]-di-μ-azido]

Fatima Setifi  1 , Zouaoui Setifi  2   1 , David K Geiger  3 , Mohammed Hadi Al-Douh  4 , Abderezak Addala  1
Affiliations

catena-Poly[[(8-amino-quinoline)-cobalt(II)]-di-μ-azido]

Fatima Setifi et al. IUCrdata. .

Abstract

The title coordination polymer, [Co(N3)2(C9H8N2)] n , was synthesized solvothermally. The CoII atom exhibits a distorted octa-hedral [CoN6] coordination geometry with a bidentate 8-amino-quinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N-H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).

Keywords: 8-amino­quinoline (8-aquin); azide anion; cobalt(II); crystal structure.

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Figures

Figure 1
Figure 1
Representation of (the title compound showing the atom-labeling scheme. Non-H atom anisotropic displacement parameters are represented at the 50% probability level. Symmetry codes: (a) −x, −y + 1, −z + 1; (b) −x + 1, −y + 1, −z + 1.
Figure 2
Figure 2
Partial packing diagram showing the polymeric chain parallel to [100]. H atoms are not shown. Symmetry codes: (a) −x, −y + 1, −z + 1; (b) −x + 1, −y + 1, −z + 1.
Figure 3
Figure 3
Partial packing diagram showing sheets parallel to (002) formed by N—H⋯N bonds. Only H atoms involved in the inter­actions are represented. Symmetry codes: (a) −x, −y + 1, −z + 1; (b) −x + 1, −y + 1, −z + 1; (c) x, y + 1, z; (d) x + 1, y + 1, z; (e). −x, −y, −z + 1.
Figure 4
Figure 4
View of the intra­chain formula image(8) N—H⋯N motif. Only H atoms involved in the hydrogen bonds are shown. Symmetry code: (a) −x, −y + 1, −z + 1.
Figure 5
Figure 5
View of the inter­chain formula image(12) N—H⋯N motif. Only H atoms involved in hydrogen bonding are shown. Symmetry code: (a) −x, −y, −z + 1.
See this image and copyright information in PMC

References

    1. Addala, A., Setifi, F., Kottrup, K. G., Glidewell, C., Setifi, Z., Smith, G. & Reedijk, J. (2015). Polyhedron, 87, 307–310.
    1. Agilent (2014). CrysAlis PRO. Oxford Diffraction Ltd, Abingdon, England.
    1. Atmani, C., Setifi, F., Benmansour, S., Triki, S., Marchivie, M., Salaün, J.-Y. & Gómez-García, C. J. (2008). Inorg. Chem. Commun.11, 921–924.
    1. Benamara, N., Setifi, Z., Yang, C.-I., Bernès, S., Geiger, D. K., Kürkçüoğlu, G. S., Setifi, F. & Reedijk, J. (2021). Magnetochemistry, 7, 50.
    1. Benmansour, S., Atmani, C., Setifi, F., Triki, S., Marchivie, M. & Gómez-García, C. J. (2010). Coord. Chem. Rev.254, 1468–1478.

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