In-situ synthesis of sunlight-driven CuO-ZnO heterostructure photocatalyst for enhanced elimination of organic pollutants and CO2 reduction

Abstract

Removing hazardous organic pollutants, such as 4-nitrophenol (4-NP) and Congo red (CR) dyes from aqueous media and CO₂ from the atmospheric medium remains a significant challenge. Herein, we report a facile in-situ synthetic approach for fabricating CuO-ZnO heterostructure photocatalysts through the surfactant-assisted co-precipitation method. The catalytic results demonstrate that the Cu₁O-ZnO photocatalyst exhibits excellent activity under direct sunlight irradiation, owing to the heterostructure formation between the CuO and ZnO. The Cu₁O-ZnO photocatalyst showed higher reaction rate constant (k) values of 0.20 min^-1 for 4-NP and 0.09 min^-1 for CR compared to previous reports. Additionally, efficient CO₂ reduction was also achieved over Cu₁O-ZnO photocatalyst. The optical and structural characterization results indicate that the improved photocatalytic reduction and degradation observed for the Cu₁O-ZnO photocatalyst can be attributed to the strong synergistic interaction between p-type CuO and n-type ZnO and the construction of the p-n heterojunction. As a result, the absorption of visible light distinctly increased and inhibited the recombination rate of the photo-created electron-hole (e^-/h⁺). Furthermore, the Cu₁O-ZnO photocatalyst exhibited remarkable durability and recyclability, retaining high photoactivity (≥ 93%) after five cycles, demonstrating its potential for real-world applications in the photocatalytic reduction and degradation reactions under direct sunlight irradiation.

Keywords: CuO-ZnO photocatalyst; charge separation; heterostructure; organic pollutants; sunlight irradiation.