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. 2024 Nov 15;14(49):36610-36621.
doi: 10.1039/d4ra06534d. eCollection 2024 Nov 11.

Synthesis of highly activated polybenzene-grafted carbon nanoparticles for supercapacitors assisted by solution plasma

Quoc Phu Phan  1   2 , Thi Cam Linh Tran  1   2 , Thanh Tung Tran  1   2 , Thi Thai Ha La  1   2 , Xuan Viet Cao  1   2 , Tuan Anh Luu  2   3 , Thi Quynh Anh Luong  2   4
Affiliations

Synthesis of highly activated polybenzene-grafted carbon nanoparticles for supercapacitors assisted by solution plasma

Quoc Phu Phan et al. RSC Adv. .

Abstract

The growing demand for electronic storage devices with faster charging rates, higher energy capacities, and longer cycle lives has led to significant advancements in supercapacitor technology. These devices typically utilize high-surface-area carbon-based materials as electrodes, which provide excellent power densities and cycling stability. However, challenges such as inadequate electrolyte interaction, hydrophobicity that impedes ion transport, and high manufacturing costs restrict their effectiveness. This study aims to enhance carbon-based materials by grafting polymer chains onto their surfaces for supercapacitor applications. A simple solution plasma process (SPP), followed by heating, prepared the polymer-grafted carbon materials. Carbon nanoparticles were synthesized from benzene through plasma discharge in liquid under ambient conditions, forming free radical sites on the carbon surface. Subsequently, benzene molecules were grafted onto the surface via radical polymerization during heating. We investigated the structural and morphological properties of the synthesized materials using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), and Raman spectroscopy. Additionally, N2 absorption-desorption isotherms were measured, pore structure was analyzed with the Dubinin-Astakhov (DA) average pore size model, and specific surface area was determined using the Brunauer-Emmett-Teller (BET) equation for all synthesized samples. The results indicated that the grafting process was influenced by heating time and drying temperature. Furthermore, the electrical properties of the samples were evaluated using cyclic voltammetry (CV), which demonstrated enhancements in both areal capacitance and cycling stability for the polybenzene-grafted carbon compared to the non-grafted variant. This research illustrates that polymer grafting can effectively improve the performance and stability of carbon-based materials for supercapacitor applications. Future work will aim to optimize these materials for broader applications.

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Conflict of interest statement

There are no conflicts to declare.

Figures

Fig. 1
Fig. 1. Reaction path for the formation of carbon products during the solution plasma process.
Fig. 2
Fig. 2. Schematic diagram of the preparation process of S-30 and S-30.H-x.D-y samples.
Fig. 3
Fig. 3. Reaction path for the formation of polybenzene-grafted carbon products during the heating process.
Fig. 4
Fig. 4. SEM images of the surface of the synthesized samples: S-30 (a and b), S-30.H-3.D-100 (c and d), S-30.H-3.D-200 (e and f), and S-30.H-6.D-200 (g and h).
Fig. 5
Fig. 5. TEM images of the surface of the synthesized samples: S-30 (a and b), S-30.H-3.D-100 (c and d), S-30.H-3.D-200 (e and f), and S-30.H-6.D-200 (g and h).
Fig. 6
Fig. 6. FTIR spectra of the S-30, S-30.H-3.D-100, S-30.H-3.D-200, and S-30.H-6.D-200 samples.
Fig. 7
Fig. 7. XRD of the S-30, S-30.H-3.D-100, S-30.H-3.D-200, and S-30.H-6.D-200 samples.
Fig. 8
Fig. 8. Specific surface area (a), BJH pore radius (b), and DA average pore size (c) of the S-30, S-30.H-3.D-100, S-30.H-3.D-200, and S-30.H-6.D-200 samples.
Fig. 9
Fig. 9. Cyclic voltammograms (a), peak potential (b), area capacitance (c), and capacitance retention (d) of the fabricated samples at a 50 mV s−1 scan rate in 0.5 N H2SO4 electrolyte.
Fig. 10
Fig. 10. Schematic illustration of the preparation process for the carbon and polybenzene-grafted carbon samples.
See this image and copyright information in PMC

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