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. 2024 Oct 8;9(Pt 10):x240968.
doi: 10.1107/S2414314624009684. eCollection 2024 Oct.

4-Bromo- N, N'-di-phenyl-benzimidamide N'-oxide

Arindam Saha  1 , Daniel Chartrand  1 , Mihaela Cibian  2 , Thierry Maris  1 , Garry S Hanan  1
Affiliations

4-Bromo- N, N'-di-phenyl-benzimidamide N'-oxide

Arindam Saha et al. IUCrdata. .

Abstract

The title compound, C19H15BrN2O, crystallizes with two similar mol-ecules in the asymmetric unit. The extended structure features dimers linked by pairs of N-H⋯O and C-H⋯O hydrogen bonds. The HNCNO moiety of the title compound shows delocalization over the N-C-N part, as evidenced by the similar C-N bond distances.

Keywords: amidine N-oxides; crystal structure; ligand synthesis.

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Figures

Figure 1
Figure 1
View of the asymmetric unit containing two independent mol­ecules with displacement ellipsoids drawn at the 50% probability level.
Figure 2
Figure 2
View of planes 1, 2, 3, 4, 5, and 6 for the phenyl rings of the mol­ecules in the asymmetric unit and hydrogen bonds (dotted lines).
Figure 3
Figure 3
View of the packing of the title compound in the unit cell.
See this image and copyright information in PMC

References

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