Recent advances in the detection of microplastics in the aqueous environment by electrochemical sensors: A review

Abstract

Microplastics (MPs), as an emerging contaminant, have become a serious threat to marine ecosystems due to their small size, widespread distribution and easy ingestion by organisms. Therefore, it is necessary to develop various analytical techniques to detect MPs in real water environment. Among these detection techniques, the advantages of electrochemical sensors, such as easy operation, high sensitivity and low cost, provide the possibility of online real-time detection of MPs in real water environment. The aim of this article is to analyze and compare the advantages and disadvantages of different MPs detection techniques. Compilation of various electrochemical sensors, we compiled various electrochemical sensors, evaluated the recent advances in carbon materials, metals and their oxides, biomass materials, composite materials, and microfluidic chips in electrochemical sensors for detecting MPs, and in-depth investigated their detection mechanisms and sensing performances, proposed hotspot nanomaterials for electrochemical sensors that could be used to detecting MPs and gave an outlook on the last years of electrochemical sensors in the area of microplastic detection. Finally, the challenges of electrochemical sensors for the detection of MPs are discussed and perspectives for this area are presented.

Keywords: Detection; Electrochemical sensor; Functional groups; Microplastics; Nanomaterials.