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. 2024:101:229-241.
doi: 10.15227/orgsyn.101.0229. Epub 2024 Jun 28.

Platinum-Catalyzed Enantioselective Diboration of Monosubstituted Alkenes

Chenpeng Gao  1 , Paul S Lee  1 , James P Morken  1
Affiliations

Platinum-Catalyzed Enantioselective Diboration of Monosubstituted Alkenes

Chenpeng Gao et al. Organic Synth. 2024.
No abstract available

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Figures

Figure 1.
Figure 1.
Color change of the reaction mixture during pre-complexation (A) The reaction mixture before heating at 80°C; (B) The heating apparatus; (C) The reaction mixture after heating at 80°C for 30 minutes.
Figure 2.
Figure 2.
Thin-layer chromatography (TLC) analysis of the reaction mixture; (A) Visualized by ceric ammonium molybdate (CAM) stain; (B) Visualized by KMnO4 stain; Left-to-right: Terminal alkene 1, pure product 3, B2pin2 2 and the reaction mixture.
Figure 3.
Figure 3.
Transformations of vicinal bis(boronic esters) arising from alkene diboration.
See this image and copyright information in PMC

References

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    1. Wang X; Wang Y; Huang W; Xia C; Wu L Direct Synthesis of Multi(boronate) Esters from Alkenes and Alkynes via Hydroboration and Boration Reactions. ACS Catal 2021, 11, 1–18.

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