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. 2025 May 8;61(39):7137-7140.
doi: 10.1039/d5cc00979k.

Spin-state modulation by host-guest chemistry with cucurbiturils

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Spin-state modulation by host-guest chemistry with cucurbiturils

Ke Lu et al. Chem Commun (Camb). .

Abstract

The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(II)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT1/2 = 77 K) via secondary coordination sphere perturbations.

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