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. 2025 Jul 24.
doi: 10.1039/d5cc01366f. Online ahead of print.

Stabilisation and functional enhancement of a metal-organic framework purinate-glass composite

Yujun Rong  1 , Ashleigh M Chester  1 , Bethan Turner  2 , Georgina P Robertson  1   3 , Ayano Kono  1 , Philip A Chater  3 , Lauren N McHugh  2 , David A Keen  4 , Thomas D Bennett  1   5 , Celia Castillo-Blas  1
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Stabilisation and functional enhancement of a metal-organic framework purinate-glass composite

Yujun Rong et al. Chem Commun (Camb). .

Abstract

The development of metal-organic framework (MOF) crystal-glass composites (CGCs) has been hindered by the scarcity of MOF glass matrices with low glass transition temperatures (Tgs). Here, we investigate a CGC consisting of a low-Tg MOF glass (agZIF-UC-7) and UiO-66. Powder X-ray diffraction and stability tests in phosphate buffer saline solution showed UiO-66 was stabilised in the glass matrix. Additionally, the composite exhibited enhanced dye uptake and gas adsorption relative to agZIF-UC-7.

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