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. 2025 Nov 11;61(91):17886-17889.
doi: 10.1039/d5cc04781a.

Size-matched supramolecular assembly between an asymmetric Anderson-type polyoxometalate hybrid and α-/γ-cyclodextrins

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Size-matched supramolecular assembly between an asymmetric Anderson-type polyoxometalate hybrid and α-/γ-cyclodextrins

Chun-Yan Liu et al. Chem Commun (Camb). .

Abstract

We report here the supramolecular assembly between a new asymmetric polyoxometalate hybrid and α-/γ-CDs, which leads to novel pseudo-rotaxane and poly-pseudo-rotaxane structures that have been thoroughly characterized in solution and in the solid state by adopting various techniques, including NMR, ESI-TOF-MS, ITC and single-crystal X-ray diffraction.

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