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. 2026 Jan 22;62(6):1986-1990.
doi: 10.1039/d5cc05936d.

Edge-centred chirality-induced enantiopure square-like sulfonylcalix[4]arene-{CoII16} cages for selective (+)-/(-)-α-pinene adsorption

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Edge-centred chirality-induced enantiopure square-like sulfonylcalix[4]arene-{CoII16} cages for selective (+)-/(-)-α-pinene adsorption

Ilia D Shutilov et al. Chem Commun (Camb). .

Abstract

A chiral recognition event plays a crucial role in fields such as pharmaceutical design, asymmetric catalysis, and racemic mixture separation. A first example is presented of new targeted square-like sulfonylcalix[4]arene-supported {CoII16}-coordination cage formation, by exploiting edge-centred chirality induction, capable of selective D-/L-α-pinene adsorption.

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