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. 1984 Jul 15;40(7):713-4.
doi: 10.1007/BF01949738.

Stereochemical course of pheromone biosynthesis in the arctiid moth, Creatonotos transiens

Stereochemical course of pheromone biosynthesis in the arctiid moth, Creatonotos transiens

T W Bell et al. Experientia. .

Abstract

The biosynthetic conversion of a pyrrolizidine alkaloid (heliotrine, IV) to a male moth pheromone (hydroxydanaidal, III) is found to proceed with inversion of configuration at the remaining asymmetric center (C-7).

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References

    1. Science. 1969 Jun 6;164(3884):1170-2 - PubMed

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