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. 1983 Jul 1;213(1):211-5.
doi: 10.1042/bj2130211.

The arsonomethyl analogue of 3-phosphoglycerate

S R Adams, M J Sparkes, H B Dixon

The arsonomethyl analogue of 3-phosphoglycerate

S R Adams et al. Biochem J. .

Abstract

4-Arsono-2-hydroxybutanoic acid, the analogue of 3-phosphoglycerate in which -CH2-AsO3H2 replaces -O-PO3H2, was synthesized. It proved to be a substrate for phosphoglycerate kinase. Its Michaelis constant was only slightly higher than that of the natural substrate, but its catalytic constant was about 1300 times smaller.

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