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. 1998 Mar;131(1):163-5.
doi: 10.1006/jmre.1997.1350.

The effects of atropisomerism and porphyrin deformation on 57Fe shieldings in superstructured hemoprotein models

I P Gerothanassis  1 , C G Kalodimos, G E Hawkes, P Haycock
Affiliations

The effects of atropisomerism and porphyrin deformation on 57Fe shieldings in superstructured hemoprotein models

I P Gerothanassis et al. J Magn Reson. 1998 Mar.

Abstract

57Fe NMR chemical shifts of superstructured heme model compounds have been found to be extremely sensitive to atropisomerism and deformation (ruffling) of the porphyrin geometry.

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