Investigation of dual-staged polymerization and secondary forming of photopultruded, fiber-reinforced, methacrylate-copolymer composites

Abstract

To develop a dual-curing monomer system for the photopultrusion of reformable (soft) composites, a microhardness assay showed that in a blend with 2,2-Bis[4-2-hydroxy-3-methacryloxypropoxy)phenyl] propane (Bis-GMA), the substitution of methyl methacrylate (MMA) for triethylene glycol dimethacrylate (TEGDMA) delayed the onset of gelation during photopolymerization. Adding lauroyl peroxide permitted the completion of polymerization thermally. This system was used to form silicate-glass-fiber-reinforced composites, with varying degrees of conversion, by photopultruding over a range of pulling speeds. Sol-gel extractions demonstrated both fully soluble and insoluble matrices. For the soluble material, gel permeation chromatography elucidated a trimodal distribution of molecular weights that corresponded to MMA, Bis-GMA, and polymeric molecules with molecular weights in the tens of thousands. Composites with matrix solubilities above about 10% wt could be swaged after photopultrusion to change the cross section from circular to rectangular before thermal processing. The effect on the final elastic modulus was small (-44GPa, as measured in flexure for 57% vol-reinforced composites); but the final flexure strength was reduced by approximately 25% to a constant of about 1.2 GPa. Morphological characteristics that were seen in the circular-sectioned precursors were observed in the swaged rectangular products as well, including flaws when swaging was conducted at matrix solubilities above about 75%.