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Mechanistic investigation of enediyne-connected amino ester rearrangement. Theoretical rationale for the exclusive preference for 1,6- or 1,5-hydrogen atom transfer depending on the substrate. A potential route to chiral naphthoazepines.
Campolo D, Gaudel-Siri A, Mondal S, Siri D, Besson E, Vanthuyne N, Nechab M, Bertrand MP. Campolo D, et al. Among authors: besson e. J Org Chem. 2012 Mar 16;77(6):2773-83. doi: 10.1021/jo202580y. Epub 2012 Feb 29. J Org Chem. 2012. PMID: 22339110
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