Near ultraviolet photochemistry of 2-bromo- and 2-iodothiophene: Revealing photoinduced ring opening in the gas phase?
Marchetti B, Karsili TN, Kelly O, Kapetanopoulos P, Ashfold MN.
Marchetti B, et al.
J Chem Phys. 2015 Jun 14;142(22):224303. doi: 10.1063/1.4921315.
J Chem Phys. 2015.
PMID: 26071706
Free article.
In both cases, the ground (X) and spin-orbit excited (X*) (where X = Br, I) atom products formed at the longest excitation wavelengths are found to recoil with fast, anisotropic velocity distributions, consistent with prompt C-X bond fission following excitation via a tran …
In both cases, the ground (X) and spin-orbit excited (X*) (where X = Br, I) atom products formed at the longest excitation wavelengths are f …