Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation

Search Page

Filters

My Custom Filters

Results by year

Table representation of search results timeline featuring number of search results per year.

Year Number of Results
1945 1
1946 3
1947 6
1948 3
1949 7
1950 10
1951 13
1952 18
1953 12
1954 9
1955 10
1956 11
1957 9
1958 7
1959 14
1960 9
1961 10
1962 6
1963 9
1964 16
1965 12
1966 23
1967 23
1968 22
1969 36
1970 33
1971 34
1972 35
1973 27
1974 30
1975 29
1976 32
1977 21
1978 29
1979 27
1980 20
1981 19
1982 21
1983 29
1984 15
1985 21
1986 30
1987 27
1988 30
1989 33
1990 24
1991 35
1992 45
1993 30
1994 32
1995 39
1996 33
1997 43
1998 45
1999 48
2000 55
2001 50
2002 71
2003 62
2004 76
2005 73
2006 63
2007 62
2008 83
2009 74
2010 117
2011 102
2012 106
2013 119
2014 122
2015 141
2016 153
2017 144
2018 145
2019 151
2020 198
2021 222
2022 242
2023 215
2024 186
2025 193
2026 1

Publication date

Text availability

Article attribute

Article type

Additional filters

Article Language

Species

Sex

Age

Other

Search Results

4,075 results

Results by year

Filters applied: . Clear all
Page 1
Recent Advances and Challenges in Barbier Polymerization.
Chen YJ, Wu LT, Xiao H, Sun XL, Wan WM. Chen YJ, et al. Chempluschem. 2023 Jan;88(1):e202200388. doi: 10.1002/cplu.202200388. Epub 2022 Dec 29. Chempluschem. 2023. PMID: 36581503 Review.
This mini review focuses on Barbier polymerization, including the brief introduction of the history and importance of polymerization methods design and the achievements of Barbier polymerization from molecular design strategies, functionalities and properties. An ou …
This mini review focuses on Barbier polymerization, including the brief introduction of the history and importance of polymerization …
Electrochemical Deoxygenative Barbier-Type Reaction.
Wang H, Wang Z, Zhao G, Ramadoss V, Tian L, Wang Y. Wang H, et al. Org Lett. 2022 May 27;24(20):3668-3673. doi: 10.1021/acs.orglett.2c01286. Epub 2022 May 17. Org Lett. 2022. PMID: 35579356
Subsequently, radical intermediates are further reduced to carbanions at the cathode, which are in situ trapped by carbonyl compounds, thus accomplishing a deoxygenative Barbier-type reaction....
Subsequently, radical intermediates are further reduced to carbanions at the cathode, which are in situ trapped by carbonyl compounds, thus …
Accessing the synthesis of natural products and their analogues enabled by the Barbier reaction: a review.
Mushtaq A, Zahoor AF, Ahmad MN, Khan SG, Akhter N, Nazeer U, Mansha A, Ahmad H, Chaudhry AR, Irfan A. Mushtaq A, et al. RSC Adv. 2024 Oct 22;14(45):33536-33567. doi: 10.1039/d4ra05646a. eCollection 2024 Oct 17. RSC Adv. 2024. PMID: 39439835 Free PMC article. Review.
The Barbier reaction is tolerant to a variety of functional groups, allowing a broad substrate scope with the employment of lanthanides, transition metals, amphoteric elements or alkaline earth metals. ...Our review provides an outlook on the synthetic applications of the …
The Barbier reaction is tolerant to a variety of functional groups, allowing a broad substrate scope with the employment of lanthanid …
Barbier Hyperbranching Polymerization-Induced Emission from an AB-Type Monomer.
Sheng YJ, Su M, Xiao H, Shi QX, Sun XL, Zhang R, Bao H, Wan WM. Sheng YJ, et al. Chemistry. 2022 Aug 26;28(48):e202201194. doi: 10.1002/chem.202201194. Epub 2022 Jul 4. Chemistry. 2022. PMID: 35655328
Herein, we report a one-pot synthesis of nonconjugated luminescent hyperbranched polymer material via Barbier hyperbranching polymerization-induced emission (PIE) from an AB-type monomer. The key step in the realization of the hyperbranched polymer is bi-functionalization …
Herein, we report a one-pot synthesis of nonconjugated luminescent hyperbranched polymer material via Barbier hyperbranching polymeri …
Barbier polymerization induced emission of cinnamaldehyde: a one-pot Grignard reaction?
Li DS, Sheng YJ, Wu LT, Chen YJ, Xiao H, Sun XL, Bao H, Wan WM. Li DS, et al. Chem Commun (Camb). 2022 Dec 1;58(96):13361-13364. doi: 10.1039/d2cc04902c. Chem Commun (Camb). 2022. PMID: 36377654
The Barbier reaction is generally regarded as a one-pot Grignard reaction. Here, the Grignard reaction of cinnamaldehyde is demonstrated to give a 1,2-addition product, while the Barbier reaction of cinnamaldehyde yields a macromolecule with interesting aggregation- …
The Barbier reaction is generally regarded as a one-pot Grignard reaction. Here, the Grignard reaction of cinnamaldehyde is demonstra …
Catalytic Asymmetric Barbier Reaction of Ketones with Unactivated Alkyl Electrophiles.
Xia H, Jiang X, Lin D, Zhang S, Yu Z, Wu X, Qu J, Chen Y. Xia H, et al. J Am Chem Soc. 2024 Oct 3. doi: 10.1021/jacs.4c10809. Online ahead of print. J Am Chem Soc. 2024. PMID: 39361011
The Barbier reaction is a reductive-type addition of an aldehyde or ketone with an organic electrophile in the presence of a terminal metal reductant, providing a straightforward and efficient method for carbon-carbon bond formation. ...Herein, we disclose a photoredox-ass …
The Barbier reaction is a reductive-type addition of an aldehyde or ketone with an organic electrophile in the presence of a terminal …
Living Covalent-Anionic-Radical Polymerization via a Barbier Strategy.
Su M, Sheng YJ, Chen YJ, Li T, Shi QX, Xiao H, Pu MQ, Bao H, Wan WM. Su M, et al. ACS Macro Lett. 2022 Mar 15;11(3):354-361. doi: 10.1021/acsmacrolett.2c00010. Epub 2022 Feb 24. ACS Macro Lett. 2022. PMID: 35575370
Here, a versatile living polymerization method is reported by introducing a well-established all-in-one covalent-anionic-radical Barbier strategy into a living polymerization. Through this living covalent-anionic-radical Barbier polymerization (Barbier CARP), …
Here, a versatile living polymerization method is reported by introducing a well-established all-in-one covalent-anionic-radical Barbier …
Mechanochemistry-Amended Barbier Reaction as an Expedient Alternative to Grignard Synthesis.
Varma Nallaparaju J, Nikonovich T, Jarg T, Merzhyievskyi D, Aav R, Kananovich DG. Varma Nallaparaju J, et al. Angew Chem Int Ed Engl. 2023 Sep 25;62(39):e202305775. doi: 10.1002/anie.202305775. Epub 2023 Jul 21. Angew Chem Int Ed Engl. 2023. PMID: 37387203
Organomagnesium halides (Grignard reagents) are essential carbanionic building blocks widely used in carbon-carbon and carbon-heteroatom bond-forming reactions with various electrophiles. In the Barbier variant of the Grignard synthesis, the generation of air- and moisture …
Organomagnesium halides (Grignard reagents) are essential carbanionic building blocks widely used in carbon-carbon and carbon-heteroatom bon …
Barbier Hyperbranching Polymerization-Induced Emission toward Facile Fabrication of White Light-Emitting Diode and Light-Harvesting Film.
Jing YN, Li SS, Su M, Bao H, Wan WM. Jing YN, et al. J Am Chem Soc. 2019 Oct 23;141(42):16839-16848. doi: 10.1021/jacs.9b08065. Epub 2019 Oct 11. J Am Chem Soc. 2019. PMID: 31577139
Here, we demonstrate a polymerization-induced emission strategy producing luminescent polymers by introducing Barbier reaction to hyperbranching polymerization, which allows luminescent properties to be easily tuned from the traditional type to an aggregation-induced emiss …
Here, we demonstrate a polymerization-induced emission strategy producing luminescent polymers by introducing Barbier reaction to hyp …
Understanding resistance.
Barbier F, Luyt CE. Barbier F, et al. Intensive Care Med. 2016 Dec;42(12):2080-2083. doi: 10.1007/s00134-016-4543-9. Epub 2016 Sep 19. Intensive Care Med. 2016. PMID: 27647333 Review. No abstract available.
4,075 results